Chad is 97% larger than Afghanistan.
Area: 652,230 km2 World Factbook
Population: 31,822,848 (July 2014) World Factbook
Afghanistan, officially the Islamic Republic of Afghanistan, is a landlocked country located in Central Asia and South Asia. It has a population of around 31 million people making it the 42nd most populous country. Wikipedia
Area: 1,284,000 km2 World Factbook
Population: 11,412,107 (July 2014) World Factbook
Chad, officially the Republic of Chad, is a landlocked country in Central Africa. It is bordered by Libya to the north, Sudan to the east, the Central African Republic to the south, Cameroon and Nigeria to the southwest and Niger to the west. Wikipedia