Western Australia (Australia) is 21% larger than Nunavut (Canada).
Western Australia is a state occupying the entire western third of Australia. It is bounded by the Indian Ocean to the north and west, the Great Australian Bight and Southern Ocean to the south, the Northern Territory to the north-east and South Australia to the south-east. Wikipedia
Nunavut is the largest, northernmost and newest territory of Canada. It was separated officially from the Northwest Territories on April 1, 1999, via the Nunavut Act and the Nunavut Land Claims Agreement Act, though the boundaries had been contemplatively drawn in 1993. Wikipedia