Ontario (Canada) is 42% larger than Chile.
Area: 756,102 km2 World Factbook
Population: 17,363,894 (July 2014) World Factbook
Chile, officially the Republic of Chile, is a South American country occupying a long, narrow strip of land between the Andes mountains to the east and the Pacific Ocean to the west. Wikipedia
Ontario is one of the ten provinces of Canada, located in east-central Canada. It is Canada's most populous province by a large margin, accounting for nearly 40% of all Canadians, and is the second largest province in total area. Wikipedia