Chile is 2.7 times larger than Ecuador.
Area: 283,561 km2 World Factbook
Population: 15,654,411 (July 2014) World Factbook
Ecuador, officially the Republic of Ecuador is a representative democratic republic in northwestern South America, bordered by Colombia on the north, Peru on the east and south, and the Pacific Ocean to the west. Wikipedia
Area: 756,102 km2 World Factbook
Population: 17,363,894 (July 2014) World Factbook
Chile, officially the Republic of Chile, is a South American country occupying a long, narrow strip of land between the Andes mountains to the east and the Pacific Ocean to the west. Wikipedia