Italy is 22 times larger than Puerto Rico.
Area: 301,340 km2 World Factbook
Population: 61,680,122 (July 2014) World Factbook
Italy, officially the Italian Republic, is a unitary parliamentary republic in Southern Europe. To the north, Italy borders France, Switzerland, Austria, and Slovenia, and is approximately delimited by the Alpine watershed, enclosing the Po Valley and the Venetian Plain. Wikipedia
Area: 13,790 km2 World Factbook
Population: 3,620,897 (July 2014) World Factbook
Puerto Rico, officially the Commonwealth of Puerto Rico, is an unincorporated territory of the United States, located in the northeastern Caribbean east of the Dominican Republic and west of both the United States Virgin Islands and the British Virgin Islands. Wikipedia