Puerto Rico is 5.3 times larger than Luxembourg.
Area: 2,586 km2 World Factbook
Population: 520,672 (July 2014) World Factbook
Luxembourg, officially the Grand Duchy of Luxembourg, is a landlocked country in Western Europe. It is bordered by Belgium to the west and north, Germany to the east, and France to the south. Wikipedia
Area: 13,790 km2 World Factbook
Population: 3,620,897 (July 2014) World Factbook
Puerto Rico, officially the Commonwealth of Puerto Rico, is an unincorporated territory of the United States, located in the northeastern Caribbean east of the Dominican Republic and west of both the United States Virgin Islands and the British Virgin Islands. Wikipedia