Mexico is 142 times larger than Puerto Rico.
Area: 1,964,375 km2 World Factbook
Population: 120,286,655 (July 2014) World Factbook
Mexico, officially the United Mexican States, is a federal republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of Mexico. Wikipedia
Area: 13,790 km2 World Factbook
Population: 3,620,897 (July 2014) World Factbook
Puerto Rico, officially the Commonwealth of Puerto Rico, is an unincorporated territory of the United States, located in the northeastern Caribbean east of the Dominican Republic and west of both the United States Virgin Islands and the British Virgin Islands. Wikipedia