Mali is 65% larger than Zambia.
Area: 1,240,192 km2 World Factbook
Population: 16,455,903 (July 2014) World Factbook
Mali, officially the Republic of Mali, is a landlocked country in West Africa. Mali is bordered by Algeria to the north, Niger to the east, Burkina Faso and Ivory Coast to the south, Guinea to the south-west, and Senegal and Mauritania to the west. Wikipedia
Area: 752,618 km2 World Factbook
Population: 14,638,505 (July 2014) World Factbook
The Republic of Zambia is a landlocked country in Southern Africa, neighboring the Democratic Republic of the Congo to the north, Tanzania to the north-east, Malawi to the east, Mozambique, Zimbabwe, Botswana and Namibia to the south, and Angola to the west. Wikipedia