Chile is 8.2 times larger than Portugal (Overseas Territories).
Area: 92,090 km2 World Factbook
Population: 10,813,834 (July 2014) World Factbook
Portugal, officially the Portuguese Republic, is a unitary semi-presidential republic. It is located in South-Western Europe, on the Iberian Peninsula, and it is the westernmost country of mainland Europe, being bordered by the Atlantic Ocean to the west and south and by Spain to the north and east. Wikipedia
Area: 756,102 km2 World Factbook
Population: 17,363,894 (July 2014) World Factbook
Chile, officially the Republic of Chile, is a South American country occupying a long, narrow strip of land between the Andes mountains to the east and the Pacific Ocean to the west. Wikipedia