Venezuela is 66 times larger than Puerto Rico.
Area: 13,790 km2 World Factbook
Population: 3,620,897 (July 2014) World Factbook
Puerto Rico, officially the Commonwealth of Puerto Rico, is an unincorporated territory of the United States, located in the northeastern Caribbean east of the Dominican Republic and west of both the United States Virgin Islands and the British Virgin Islands. Wikipedia
Area: 912,050 km2 World Factbook
Population: 28,868,486 (July 2014) World Factbook
Venezuela, officially called the Bolivarian Republic of Venezuela, is a country on the northern coast of South America. Venezuela's territory covers around 916,445 square kilometres with an estimated population of approximately 29,100,000. Wikipedia