Rio de Janeiro (Brazil) is 66% larger than Rwanda.
Area: 26,338 km2 World Factbook
Population: 12,337,138 (July 2014) World Factbook
Rwanda, officially the Republic of Rwanda, is a sovereign state in central and east Africa. Located a few degrees south of the Equator, Rwanda is bordered by Uganda, Tanzania, Burundi and the Democratic Republic of the Congo. Wikipedia
Rio de Janeiro is one of the 27 states of Brazil. It has the third largest economy of Brazil, with the largest being that of the state of São Paulo, and the second being that of Minas Gerais. The state of Rio de Janeiro is located within the Brazilian geopolitical region classified as the Southeast. Wikipedia