New South Wales (Australia) is 39 times larger than Slovenia.
Area: 20,273 km2 World Factbook
Population: 1,988,292 (July 2014) World Factbook
Slovenia, officially the Republic of Slovenia, is a nation state in southern Central Europe at the crossroads of main European cultural and trade routes. It borders Italy to the west, Austria to the north, Croatia to the south and southeast, and Hungary to the northeast. Wikipedia
New South Wales (abbreviated as NSW), is Australia's most populous state, and is located in the south-east of the country, north of Victoria, south of Queensland, east of South Australia, west of Jervis Bay Territory and encompasses the whole of the Australian Capital Territory. Wikipedia