Chad is 71% larger than Zambia.
Area: 1,284,000 km2 World Factbook
Population: 11,412,107 (July 2014) World Factbook
Chad, officially the Republic of Chad, is a landlocked country in Central Africa. It is bordered by Libya to the north, Sudan to the east, the Central African Republic to the south, Cameroon and Nigeria to the southwest and Niger to the west. Wikipedia
Area: 752,618 km2 World Factbook
Population: 14,638,505 (July 2014) World Factbook
The Republic of Zambia is a landlocked country in Southern Africa, neighboring the Democratic Republic of the Congo to the north, Tanzania to the north-east, Malawi to the east, Mozambique, Zimbabwe, Botswana and Namibia to the south, and Angola to the west. Wikipedia