Manila is 96 times larger than Vatican.
Area: 0 km2 World Factbook
Population: 842 (July 2014) World Factbook
Vatican City, officially Vatican City State, is one of the last six remaining absolute monarchies whose territory consists of a walled enclave within the city of Rome. It has an area of approximately 44 hectares, and a population of around 840. Wikipedia
Area: 42 km2 calculated
Manila is the capital and second largest city of the Philippines. It is one of the sixteen cities which, along with the municipality of Pateros, make up Metro Manila, the National Capital Region, whose overall population is around 12 million. Wikipedia