South Australia (Australia) is 31% larger than Zambia.
Area: 752,618 km2 World Factbook
Population: 14,638,505 (July 2014) World Factbook
The Republic of Zambia is a landlocked country in Southern Africa, neighboring the Democratic Republic of the Congo to the north, Tanzania to the north-east, Malawi to the east, Mozambique, Zimbabwe, Botswana and Namibia to the south, and Angola to the west. Wikipedia
South Australia is a state in the southern central part of Australia. It covers some of the most arid parts of the continent. With a total land area of 983,482 square kilometres, it is the fourth largest of Australia's states and territories. Wikipedia